The broadcast, or rather the first part of it, will be aired between between 17:00 and 18:00 local time, with no real details about who is going to be featured on that portion of the card. We then take a 4 hour break before returning at 22:00 local time for one hour, according to the schedule on TV Mao.
With just 5 bouts schedule for the card and only 2 time slots of one hour each it'll be interesting to see how CCTV5 air the show, with the likely idea being that they will have a lot of things going on at the venue between bouts. Likely allowing us to watch the WBA Super Bantamweight title bout between Nehomar Cermeno (24-5-1, 14) and Nop Kratingdaenggym (17-0, 5) [ณพ ฐิติพงศกร] and one other bout.
Interestingly http://sports.le.com/ seem to be suggesting that they will be streaming the card from 19:30 local time, adding further confusion to those wanting to watch the show.
It's a confusing situation but it's almost certain that all the footage from the show will hit the internet not too long after the shot it's self.